Local Atomic Structure in Photoisomerized Ruthenium Sulfur Dioxide Complexes Revealed by Pair Distribution Function Analysis

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Local Atomic Structure Analysis Using the Atomic Pair Distribution Method

Powder diffraction is a major component of any condensed matter scientist’s arsenal, providing the investigator a way to directly map the location of atoms inside of a material. The most common diffraction experiments provide insights into the average atomic structure of materials, which can break down when materials have lowered local symmetry, or are disordered. Analysis of the pair distribut...

متن کامل

Light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes.

The irradiation of ruthenium-sulfur dioxide complexes of general formula trans-[Ru(II)(NH(3))(4)(SO(2))X]Y with laser light at low temperature results in linkage isomerization of SO(2), starting with eta(1)-planar S-bound to eta(2)-side S,O-bound SO(2). The solid-state photoreaction proceeds with retention of sample crystallinity. Following work on trans-[Ru(NH(3))(4)Cl(eta(1)-SO(2))]Cl and tra...

متن کامل

Structure of nanocrystalline Ti3C2 MXene using atomic pair distribution function.

The structures of nanocrystalline pristine, potassium hydroxide and sodium acetate intercalated new two-dimensional materials Ti3C2 MXenes were studied using the x-ray atomic pair distribution function technique. Pristine MXene has a hexagonal structure with a=b=3.0505(5)  Å, c=19.86(2)  Å (S.G. P63/mmc No. 194). Both hydroxyl and fluoride terminating species are present. The intercalation of K...

متن کامل

Probing the local structure of doped manganites using the atomic pair distribution function

We have used atomic pair distribution function (PDF) analysis based on neutron powder diffraction data to investigate the local structure of the colossal magnetoresistant manganite La0.75Ca0.25MnO3 as a function of temperature. In the doping range 0.17 < x < 0.5 these materials show a metal-to-insulator transition, transforming from a ferromagnetic metal (FM) at low temperature to a paramagneti...

متن کامل

Local structural studies of Ba(1-x)K(x)Fe2As2 using atomic pair distribution function analysis.

Systematic local structural studies of the Ba(1-x)K(x)Fe(2)As(2) system are undertaken at room temperature using atomic pair distribution function analysis. The local structure of the Ba(1-x)K(x)Fe(2)As(2) is found to be well described by the long-range structure extracted from diffraction experiments, but with anisotropic atomic vibrations of the constituent atoms (U11 = U22 not equal U33). Th...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: The Journal of Physical Chemistry C

سال: 2020

ISSN: 1932-7447,1932-7455

DOI: 10.1021/acs.jpcc.0c00634